|
|
kanosamine_6-phosphate <=> Aminofructose_6-phosphate
|
5.3.1
|
–
|
| |
KEGG:
R06589
MetaCyc:
RXN-9582
|
|
|
|
kanosamine + ATP <=> H+ + kanosamine_6-phosphate + ADP
|
2.7.1.179
kanosamine kinase
|
–
|
| |
BRENDA:
BR50542
KEGG:
R06588
MetaCyc:
RXN-9581
SABIO-RK:
6163
|
|
|
|
Demethyl-desacetyl-rifamycin_S <=> 27-O-Demethyl-25-O-desacetylrifamycin_SV
|
not assigned
|
–
|
| |
KEGG:
R06996
|
|
|
|
Rifamycin_W-hemiacetal <=> Demethyl-desacetyl-rifamycin_S
|
not assigned
|
–
|
| |
KEGG:
R06994
|
|
|
|
AminoDAHP <=> AminoDHQ + phosphate
|
4.2.1.M26
|
–
|
| |
KEGG:
R06592
MetaCyc:
RXN-9585
|
|
|
|
UDP-glucose + NAD+ <=> H+ + UDP-3-ketoglucose + NADH
|
1.1.1
1.1.1.M53
|
–
–
|
| |
KEGG:
R06594
MetaCyc:
RXN-9578
|
|
|
|
UDP-glucose + N-Demethylansamitocin_P-3 <=> UDP + Ansamitocinoside_P-3
|
2.4.1
|
–
|
| |
KEGG:
R09857
|
|
|
|
Ansamitocinoside_P-3 + Carbamoyl_phosphate <=> 4''''-O-Carbamoyl_ansamitocinoside_P-3 + phosphate
|
2.1.3
|
–
|
| |
KEGG:
R09858
|
|
|
|
Aminofructose_6-phosphate + D-ribose_5-phosphate <=> Iminoerythrose_4-phosphate + sedoheptulose_7-phosphate
|
2.2.1.1
transketolase
|
–
|
| |
KEGG:
R06590
|
|
|
|
Rifamycin_W <=> Rifamycin_Z
|
not assigned
|
–
|
| |
KEGG:
R06993
|
|
|
|
Rifamycin_W <=> Rifamycin_W-hemiacetal
|
not assigned
|
–
|
| |
KEGG:
R06992
|
|
|
|
S-adenosyl-L-methionine + 27-O-demethylrifamycin_SV <=> S-adenosyl-L-homocysteine + rifamycin_SV + H+
|
2.1.1.315
27-O-demethylrifamycin SV methyltransferase
|
–
|
| |
BRENDA:
BR51221
KEGG:
R06998
MetaCyc:
RXN-9611
|
|
|
|
UDP-alpha-D-kanosamine <=> kanosamine
|
not assigned
|
–
|
| |
KEGG:
R06587
|
|
|
|
Proansamitocin <=> 19-Chloroproansamitocin
|
not assigned
|
–
|
| |
KEGG:
R09851
|
|
|
|
rifamycin_SV <=> Rifamycin_B
|
not assigned
|
–
|
| |
KEGG:
R06600
|
|
|
|
27-O-Demethyl-25-O-desacetylrifamycin_SV + acetyl-CoA <=> 27-O-demethylrifamycin_SV + CoA
|
2.3.1
|
–
|
| |
KEGG:
R06997
MetaCyc:
RXN-9610
|
|
|
|
N-Demethyl-desepoxymaytansinol + isobutyryl-CoA <=> N-Demethyl-desepoxyansamitocin_P-3 + CoA
|
not assigned
|
–
|
| |
KEGG:
R09854
|
|
|
|
rifamycin_SV <=> rifamycin_S
|
not assigned
|
–
|
| |
KEGG:
R06999
|
|
|
|
Iminoerythrose_4-phosphate + phosphoenolpyruvate + H2O <=> AminoDAHP + phosphate
|
2.5.1
|
–
|
| |
KEGG:
R06591
MetaCyc:
RXN-9584
|
|
|
|
19-Chloroproansamitocin <=> 20-O-Methyl-19-chloroproansamitocin
|
not assigned
|
–
|
| |
KEGG:
R09852
|
|
|
|
34a-Deoxy-rifamycin_W <=> Rifamycin_W
|
not assigned
|
–
|
| |
KEGG:
R06991
|
|
|
|
Proansamycin_X <=> Protorifamycin_I
|
not assigned
|
–
|
| |
KEGG:
R06597
|
|
|
|
5-amino-5-deoxy-3-dehydroshikimate <=> H+ + 3-amino-5-hydroxybenzoate + H2O
|
4.2.1.144
3-amino-5-hydroxybenzoate synthase
|
–
|
| |
BRENDA:
BR50552
KEGG:
R06595
MetaCyc:
RXN-9587
|
|
|
|
Rifamycin_Z <=> Demethyl-desacetyl-rifamycin_S
|
not assigned
|
–
|
| |
KEGG:
R06995
|
|
|
|
N-Demethyl-desepoxyansamitocin_P-3 <=> N-Demethylansamitocin_P-3
|
not assigned
|
–
|
| |
KEGG:
R09855
|
|
|
|
20-O-Methyl-19-chloroproansamitocin + Carbamoyl_phosphate <=> N-Demethyl-desepoxymaytansinol + phosphate
|
2.1.3
|
–
|
| |
KEGG:
R09853
|
|
|
|
Proansamycin_X <=> 34a-Deoxy-rifamycin_W
|
not assigned
|
–
|
| |
KEGG:
R06599
|
|
|
|
S-adenosyl-L-methionine + N-Demethylansamitocin_P-3 <=> S-adenosyl-L-homocysteine + Ansamitocin_P-3
|
2.1.1
|
–
|
| |
KEGG:
R09856
|
|
|
|
UDP-3-ketoglucose + L-glutamate <=> UDP-alpha-D-kanosamine + 2-oxoglutarate
|
2.6.1
|
–
|
| |
KEGG:
R06586
|
|
|
|
AminoDHQ <=> 5-amino-5-deoxy-3-dehydroshikimate + H2O
|
4.2.1.M25
|
–
|
| |
KEGG:
R06593
MetaCyc:
RXN-9586
|
|
